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High-Performance Silicon Nitride Ceramics for Industrial Needs High Hardness and Thermal Insulation
Introduction
Silicon Nitride (Si₃N₄) ceramic is a high-performance advanced
ceramic material produced by high-temperature sintering of silicon
nitride powder. It is renowned for its unique combination of
properties, including extremely high hardness, outstanding fracture
toughness, excellent thermal insulation (low thermal conductivity),
and remarkable thermal shock resistance. This material excels in
extreme environments, making it an ideal choice for addressing
needs related to wear resistance, thermal insulation, and
lightweighting in many high-end industrial fields.
Applications
Leveraging its hardness and thermal insulation properties, silicon
nitride ceramics are widely used across various high-tech sectors:
High-Temperature Insulation Components: Used as kiln insulation linings and thermocouple protection tubes in metallurgy and glass industries, effectively reducing heat loss and withstanding high temperatures.
Wear-Resistant Sealing Applications: Serve as mechanical seal rings for pumps, especially in high-temperature and highly corrosive media, where their hardness and wear resistance ensure long life and reliability.
Aerospace: Used in engine components and combustion chamber liners, utilizing their high-temperature resistance, thermal insulation, and lightweight (compared to metals) properties.
Electronics Industry: Used as paddles and rollers in diffusion furnaces and CVD equipment for semiconductor manufacturing, where their high purity and thermal insulation prevent contamination and heat transfer.
Military Protection: Used in transparent armor and ballistic ceramics, as their high hardness effectively resists impact.
Advantages
High Hardness and Wear Resistance: High Vickers hardness, second only to a few materials, with extremely excellent wear resistance and long service life.
Excellent Thermal Insulation (Low Thermal Conductivity): Thermal conductivity is much lower than metals, making it an excellent high-temperature insulating material that effectively blocks heat transfer, saving energy and reducing consumption.
High Strength and High Toughness: Fracture toughness is several times that of alumina ceramics, with excellent resistance to mechanical shock and thermal shock, and less prone to brittle fracture.
High-Temperature and Corrosion Resistance: Maintains strength at high temperatures up to 1200°C and has good resistance to most acids and alkalis.
Low Density and Self-Lubrication: Lightweight, reducing system load, and with a low friction coefficient for smoother operation.
Specifications Table
| Parameter | Typical Indicators / Specifications |
|---|---|
| Main Composition | Si₃N₄ |
| Bulk Density | 3.2 - 3.3 g/cm³ |
| Vickers Hardness (HV) | 1400 - 1600 |
| Fracture Toughness | 6 - 8 MPa·m¹/² |
| Flexural Strength | 600 - 800 MPa (Room Temperature) |
| Thermal Conductivity | 15 - 25 W/(m·K) (Much lower than metals) |
| Maximum Service Temperature | 1200 °C (in air) |
| Coefficient of Thermal Expansion | 3.0 - 3.5 × 10⁻⁶/°C (20-1000°C) |
| Dielectric Strength | > 15 kV/mm |
Manufacturing Process
Nitridation of high-purity silicon powder → Obtain silicon nitride
powder → Add sintering aids → Ball milling and mixing → Spray
granulation → Dry pressing/Cold isostatic pressing (CIP) → Gas
pressure sintering (GPS) or Hot pressing (HP) → Precision machining
(diamond grinding) → Non-destructive testing → Finished product
inspection.
Usage Instructions
Pre-Installation: Check the ceramic component for defects such as cracks or chipped edges. Although it has relatively good toughness, it is still a brittle material and should be protected from rough impact.
During Installation: Ensure even force application. For seals, use specialized tools to tighten bolts uniformly to prevent damage from unilateral stress.
Operation: Although it has good thermal shock resistance, it is still advisable to avoid sudden and severe temperature changes to extend its service life.
Maintenance: Regularly inspect the system status. If abnormal wear or performance degradation is found, investigate and replace promptly.
After-Sales Service
We provide professional technical consultation and selection
support. The product warranty period is 12 months. Custom
non-standard sizes are supported, and detailed product performance
test reports and usage guidance are provided. We承诺 (commit to) free
repair or replacement for issues caused by material or
manufacturing defects.
FAQ
Q1: Which is harder, silicon nitride ceramic or alumina ceramic?
A1: The Vickers hardness of silicon nitride ceramic (HV 1400-1600)
is slightly lower than that of high-purity alumina ceramic (HV
1600+), but its fracture toughness is much higher than alumina,
giving it greater overall resistance to damage and better impact
resistance.
Q2: Is its thermal insulation performance better than zirconia
ceramic?
A2: No. Zirconia ceramic has very low thermal conductivity (~2-3
W/m·K) and is an excellent thermal insulator. The thermal
conductivity of silicon nitride (15-25 W/m·K) is higher than
zirconia but still significantly lower than metals, placing it in
the category of thermal insulating materials, while its mechanical
strength is much higher than zirconia.
Q3: Why is it much more expensive than alumina ceramic?
A3: The main reasons are high raw material costs and complex
sintering processes. Silicon nitride powder is difficult to produce
and requires high-temperature sintering under high-pressure
nitrogen atmosphere, resulting in high equipment investment and
energy consumption costs.

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